1. A catback exhaust is only for making more noise. It doesn't have any measurable improvement on torque output. Catted/cattless downpipes have nominal impact on torque output, unless you modifying heavily. With a JB4, I would consider them of no meaningful benefit. Certainly not worth the pain in the ass and breaking the law to install.
2. Octane boosters are ok once in a while. You don't want to run them for daily driving as the MMT in them will ruin your catalytic converters, foul up the plugs and have other negative consequences. I know of one person who had done it in the ATS-Vs long term, but I would not do it. I would suggest a gallon or two of E85 per tank, which essentially acts as an octane booster.
Generally, talk to Tapout about what you should or should not do.
Do keep in mind that he is incentivized to sell parts.... Do also keep in mind that the recommended by him Brisk spark plugs will only last 10k at the most. They are a bit of a pain in the ass to replace, so unless you are ok with this replacement interval, I would stick with Acdelco OEM or NGK ruthenium, both gapped tighter (probably .027-.025" depending on max boost). But I would plan on plugs with a tighter gap and since you are taking them out, might as well put in new ones.